ChemInform Abstract: Homogeneous Catalysis of Silane Alcoholysis via Nucleophilic Attack by the Alcohol on an Ir(η2‐HSiR3) Intermediate Catalyzed by (IrH2S2(PPh3)2)SbF6 (S: Solvent).

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    • Abstract:
      Lewis acidic metal complexes such as (I) are very efficient and highly selective catalysts for silane alcoholysis.