Effects of RE³⁺ Ionic Radius on Monoclinic Phase Content of 8 mol% REO1.5 Partially Stabilized ZrO2 (RE = Yb, Y, Gd, and Nd) Powder Compacts after Annealing at High Temperature.

Powders of zirconia doped with 8 mol% REO1.5 ( RE = Yb, Y, Gd, and Nd) were synthesized by using the sol-spray pyrolysis method. The effects of RE³⁺ ionic radius on monoclinic (m) phase content of powders were investigated. The XRD results showed that the metastable tetragonal (t′) phase underwent a complete phase change to form m and cubic (c) phases after a heat treatment of 50-100 h at 1450°C. A cation size-dependent reduction in the m phase content of the REO1.5 partially stabilized ZrO2 powders was observed. The SEM- EDS analysis of the powders revealed that the RE³⁺ concentrations in the c phases decreased with decreasing the RE³⁺ ionic radius. These results indicate that the stabilizer concentration of the c phase can be attributed to RE³⁺ ionic radii, resulting in different m phase contents. Compared to the REO1.5 single doped ZrO2, the m phase contents of 8 mol% ( RE0.5Yb0.5)- ZrO2 ( RE = Y, Gd, and Nd) powders were significantly reduced. The results prove that the stabilizer with a lower RE³⁺ size is effective in reducing the m phase content of partially stabilized ZrO2 after annealing at high temperatures. [ABSTRACT FROM AUTHOR]

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