An Advanced 3D Crosslinked Conductive Binder for Silicon Anodes: Leveraging Glycerol Chemistry for Superior Lithium-Ion Battery Performance.

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Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 0370543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3773 (Electronic) Linking ISSN: 14337851 NLM ISO Abbreviation: Angew Chem Int Ed Engl Subsets: MEDLINE

Publication: <2004-> : Weinheim : Wiley-VCH
Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962-

Silicon (Si) anodes hold great promise for high-capacity lithium-ion batteries (LIBs), yet their practical application is hindered by severe volume expansion and mechanical degradation. To tackle these challenges, we present an innovative 3D crosslinked conductive polyoxadiazole (POD) binder engineered with glycerol (GL) to form a robust network of covalent and hydrogen bonds. This unique chemical architecture not only enhances adhesion and mechanical resilience to effectively dissipate the stresses induced by Si's volumetric changes but also constructs a robust conductive framework to facilitate electron transfer. The dynamic interplay between strong covalent and flexible hydrogen bonds in the POD-c-GL binder enables superior structural integrity and stable solid-electrolyte interphase (SEI) during cycling. The Si@POD-c-GL anode exhibits remarkable electrochemical performance, including a high initial Coulombic efficiency, impressive rate capability, and outstanding cycling stability. This work highlights the potential of harnessing in situ crosslinking chemistry to develop advanced binders, paving the way for the next generation of high-performance Si anodes in LIBs.
(© 2024 Wiley-VCH GmbH.)

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2022YFA1205201 the National Key Research and Development Plan; sklpme2022-2-04 the State Key Laboratory of Polymer Materials Engineering

Keywords: 3D crosslinking chemistry; lithium-ion batteries; polymer binder; silicon anode; stress dissipation

Date Created: 20241129 Latest Revision: 20241209

20241210

10.1002/anie.202418794

39614127