Catalytic Hydroconversion of 5-HMF to Value-Added Chemicals: Insights into the Role of Catalyst Properties and Feedstock Purity.

Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 101319536 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1864-564X (Electronic) Linking ISSN: 18645631 NLM ISO Abbreviation: ChemSusChem Subsets: MEDLINE

Original Publication: Weinheim : Wiley-VCH

Biofuels* ; Furaldehyde*/analogs & derivatives ; Furaldehyde*/chemistry; Catalysis ; Hydrogenation

5-hydroxymethylfurfural (HMF) is an important bio-derived platform molecule that is generally obtained from hexoses via acid-catalyzed dehydration. It can be effectively transformed into a variety of value-added derivatives, thus being an ideal candidate for fossil replacement. Both HMF oxidation and hydrogenation processes enable the synthesis of numerous chemicals, monomers for polymerization, and biofuel precursors. This Review summarizes the most recent advances in heterogeneous catalytic hydroconversion of HMF into valuable chemicals with strong focus on 2,5-bishydroxymethyl furan (BHMF), 2,5-bishydroxymethyltetrahydrofuran (BHMTHF), and 2,5-dimethyltetrahydrofuran (DMTHF). In addition, multifunctional catalytic systems that enable a tunable production of various HMF derived intermediates are discussed. Within this chemistry, the surprising impact of HMF purity on the catalytic performance, such as selectivity and activity, during its upgrading is highlighted. Lastly, the remaining challenges in the field of HMF hydroconversion to the mentioned chemicals are summarized and discussed, taking into account the knowledge gain of catalyst properties and feedstock purity.
(© 2022 Wiley-VCH GmbH.)

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HBC.2017.0597 Sugar-based chemicals and Polymers through Innovative Chemocatalysis and engineered Yeast

Keywords: 5-hydroxymethylfurfural; biomass; heterogeneous catalysis; impurities; platform chemicals

0 (Biofuels)
70ETD81LF0 (5-hydroxymethylfurfural)
DJ1HGI319P (Furaldehyde)

Date Created: 20220329 Date Completed: 20220711 Latest Revision: 20220711

20221213

10.1002/cssc.202200412

35348300