Recent advances in photoinduced electron transfer processes of fullerene-based molecular assemblies and nanocomposites.

Item request has been placed! ×
Item request cannot be made. ×
loading   Processing Request
Read More Add to Saved list
  • Author(s): Ito O;Ito O; D'Souza F
  • Source:
    Molecules (Basel, Switzerland) [Molecules] 2012 May 16; Vol. 17 (5), pp. 5816-35. Date of Electronic Publication: 2012 May 16.
  • Publication Type:
    Journal Article; Research Support, Non-U.S. Gov't; Review
  • Language:
    English
  • Additional Information
    • Source:
      Publisher: MDPI Country of Publication: Switzerland NLM ID: 100964009 Publication Model: Electronic Cited Medium: Internet ISSN: 1420-3049 (Electronic) Linking ISSN: 14203049 NLM ISO Abbreviation: Molecules Subsets: MEDLINE
    • Publication Information:
      Original Publication: Basel, Switzerland : MDPI, c1995-
    • Subject Terms:
      Electrons*; Fullerenes/*chemistry ; Nanocomposites/*chemistry ; Porphyrins/*chemistry; Electron Transport ; Fluorescence ; Indoles/chemistry ; Isoindoles ; Kinetics ; Models, Molecular ; Photochemical Processes ; Photosensitizing Agents/chemistry ; Spectrometry, Fluorescence
    • Abstract:
      Photosensitized electron-transfer processes of fullerenes hybridized with electron donating or other electron accepting molecules have been surveyed in this review on the basis of the recent results reported mainly from our laboratories. Fullerenes act as photo-sensitizing electron acceptors with respect to a wide variety of electron donors; in addition, fullerenes in the ground state also act as good electron acceptors in the presence of light-absorbing electron donors such as porphyrins. With single-wall carbon nanotubes (SWCNTs), the photoexcited fullerenes act as electron acceptor. In the case of triple fullerene/porphyrin/SWCNT architectures, the photoexcited porphyrins act as electron donors toward the fullerene and SWCNT. These mechanisms are rationalized with the molecular orbital considerations performed for these huge supramolecules. For the confirmation of the electron transfer processes, transient absorption methods have been used, in addition to time-resolved fluorescence spectral measurements. The kinetic data obtained in solution are found to be quite useful to predict the efficiencies of photovoltaic cells.
    • References:
      Chem Rev. 2010 Nov 10;110(11):6768-816. (PMID: 20364812)
      Chemistry. 2005 Jul 18;11(15):4416-28. (PMID: 15883985)
      Chemphyschem. 2011 Aug 22;12(12):2266-73. (PMID: 21751336)
      ACS Appl Mater Interfaces. 2011 Jul;3(7):2368-76. (PMID: 21623633)
      Chem Soc Rev. 2009 Jan;38(1):165-84. (PMID: 19088972)
      Chemphyschem. 2003 Apr 14;4(5):474-81. (PMID: 12785261)
      Chem Commun (Camb). 2012 Apr 14;48(30):3641-3. (PMID: 22391474)
      Phys Chem Chem Phys. 2005 Sep 7;7(17):3163-71. (PMID: 16240027)
      Phys Chem Chem Phys. 2010 Jan 7;12(1):44-57. (PMID: 20024442)
      J Am Chem Soc. 2012 Jan 11;134(1):654-64. (PMID: 22112019)
      Phys Chem Chem Phys. 2012 Feb 28;14(8):2940-50. (PMID: 22262196)
      Angew Chem Int Ed Engl. 2009;48(41):7655-9. (PMID: 19739154)
      Chem Soc Rev. 2002 Jan;31(1):22-36. (PMID: 12108980)
      Chem Commun (Camb). 2010 Dec 14;46(46):8749-51. (PMID: 20967352)
      J Am Chem Soc. 2001 Jun 6;123(22):5277-84. (PMID: 11457390)
      Chem Commun (Camb). 2009 Sep 7;(33):4913-28. (PMID: 19668806)
      J Phys Chem B. 2005 May 26;109(20):10107-14. (PMID: 16852225)
      Chem Rev. 2006 Mar;106(3):1105-36. (PMID: 16522018)
      Chem Soc Rev. 2012 Jan 7;41(1):86-96. (PMID: 21975532)
      Acc Chem Res. 2009 Dec 21;42(12):1890-8. (PMID: 19902921)
      J Am Chem Soc. 2010 Jun 16;132(23):8158-64. (PMID: 20499875)
      Acc Chem Res. 2002 Dec;35(12):1026-34. (PMID: 12484790)
      J Am Chem Soc. 2007 Dec 26;129(51):15865-71. (PMID: 18052162)
      J Am Chem Soc. 2011 Dec 14;133(49):19922-30. (PMID: 22088093)
    • Accession Number:
      0 (Fullerenes)
      0 (Indoles)
      0 (Isoindoles)
      0 (Photosensitizing Agents)
      0 (Porphyrins)
      V5PUF4VLGY (phthalocyanine)
    • Publication Date:
      Date Created: 20120518 Date Completed: 20120820 Latest Revision: 20211203
    • Publication Date:
      20221213
    • Accession Number:
      PMC6268260
    • Accession Number:
      10.3390/molecules17055816
    • Accession Number:
      22592087