Excellent luminescent thermal stability of Dy³⁺/Sm³⁺ co-activated multifunctional titanate single-phase phosphors.

Nowadays, the development of phosphors with excellent luminescent thermal stability for various applications has become a research hotspot. Therefore, the Dy3+/Sm3+ co-activated multifunctional NaYTiO4 phosphors with excellent comprehensive performance in the field of non-contact optical measurement and white LED solid-state lighting were reported in this paper, and their crystal structure, elemental composition, optical bandgap and photoluminescence properties were systematically studied. Remarkably, the reason why NaYTiO4:Dy3+,Sm3+ phosphors achieved color-controlled emission from yellow to orange-red and even to white at the excitation wavelength of 363 nm was not based on the energy transfer process from Dy3+ to Sm3+ but on co-excitation. When the temperature reached 475 K, the luminescence intensity of the phosphor still maintained 96.75% of the initial intensity, demonstrating excellent thermal quenching property. Furthermore, the temperature sensing performance was evaluated by FIR technique according to the differential decreasing trend of Dy3+ and Sm3+ emission intensity with increasing temperature. Finally, we also certified the applicability of NaYTiO4:Dy3+,Sm3+ phosphors in white LEDs for indoor health lighting. These results indicate that NaYTiO4:Dy3+,Sm3+ multifunctional phosphors are promising dual functional luminescent platforms that can be used for non-contact optical thermometers and white LED device applications. [ABSTRACT FROM AUTHOR]

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