Cocoa olein glycerolysis with lipase Candida antarctica in a solvent free system.

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    • Alternate Title:
      Glicerólisis de oleínas de cacao con lipasa Candida antarctica en un sistema libre de solventes.
    • Subject Terms:
      COCOA; CANDIDA; DIGLYCERIDES; MONOGLYCERIDES; OLEIC acid; LIPASES; FREE fatty acids; WASTE products
    • Abstract:
      En el presente trabajo se pretende valorizar la oleína vegetal de cacao procedente de la ruptura ácida de las pastas de refinación química. El objetivo es poner a punto un proceso de glicerólisis enzimática en un sistema libre de solventes maximizando la producción de monoglicéridos (MAG) y diglicéridos (DAG). Se ha estudiado el efecto de la dosis de enzima, el contenido de glicerol y el tiempo de reacción, la modificación de la presión de reacción y la composición de la materia prima. Se concluye que el rendimiento de la reacción aumenta hasta el 90-95% cuando se aplica un vacío de 2-3 mbar a 65 °C suficiente para evaporar el agua que se va generando como producto, una dosis de enzima del 1% y una relación molar aceite:glicerol 1:2. El mayor rendimiento en cuanto a la producción de MAG y DAG se ha conseguido partiendo de una materia prima rica en acidez libre (FFA), obteniéndose un aceite con un 33.4 y 44.2% de MAG y DAG, respectivamente. Se observa que los tiempos de reacción son cortos (6-8h) comparados con los descritos en la bibliografía encontrada (24h). [ABSTRACT FROM AUTHOR]
    • Abstract:
      In this paper we present the valorization of cocoa olein obtained from the acid fat-splitting of soapstocks. The aim is to develop a solvent free process (enzymatically catalyzed) to maximize the production of a final product with high content of monoglycerides (MAG) and diglycerides (DAG). The effect of the enzyme dose, glycerol content, reaction times as well as the modification of the raw material and pressure were studied. The yield of the reaction increased up to 90-95% when using a vacuum of 2-3 mbar at 65 °C, enough to evaporate the water which is generated as a by-product, an enzyme dose of 1% and molar ratio oil:glycerol of 1:2. The highest yield in terms of MAG and DAG production was obtained by starting from a raw material which was rich in free acidity (FFA), rendering oil with 33.4 and 44.2% MAG and DAG, respectively. Short reaction times (6-8 h) were observed compared to previously reported results (24 h). [ABSTRACT FROM AUTHOR]
    • Abstract:
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