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A parallelogram metallomacrocycle bearing self-catenation and its derivative supramolecular isomerism.
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- Author(s): Wang, Jun1 (AUTHOR); Zhao, He1 (AUTHOR); Chen, Mingzhao2 (AUTHOR) ; Jiang, Zhiyuan1 (AUTHOR); Wang, Feng1 (AUTHOR); Liu, Die2 (AUTHOR); Jiang, Zhilong2 (AUTHOR); Xie, Ting-Zheng2 (AUTHOR); Zhang, Zhe2 (AUTHOR); Wang, Pingshan1,2 (AUTHOR)
- Source:
Chemical Communications. 8/4/2020, Vol. 56 Issue 60, p8444-8447. 4p.- Subject Terms:
- Source:
- Additional Information
- Abstract: Macrocycle-based architectures are of importance in synthetic chemistry. Here, a novel parallelogram metallomacrocycle Fe2(LA)2 with reversible structural transformation was designed and synthesized. The template-free metalla[2]catenane [Fe2(LA)2]2 could be obtained by changing the concentration and has been monitored on the basis of NMR analysis. By redesigning the metallo-ligand, a catenane-like intersected parallelogram assembly with two shape-persistent supramolecular isomers was achieved. This work develops the field of terpyridine-based macrocycle system research and is valuable for obtaining other types of supramolecular isomerism. [ABSTRACT FROM AUTHOR]
- Abstract: Copyright of Chemical Communications is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
- Abstract:
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