Electrodeposition of Zn-Al-Layered Double Hydroxides With Interlayer Modification by Ibuprofen as Fiber Coating for Solid Phase Microextraction of Nonsteroidal Anti-Inflammatory Drugs.

Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 101088554 Publication Model: Print Cited Medium: Internet ISSN: 1615-9314 (Electronic) Linking ISSN: 16159306 NLM ISO Abbreviation: J Sep Sci Subsets: MEDLINE

Original Publication: Weinheim, Germany : Wiley-VCH, c2001-

Anti-Inflammatory Agents, Non-Steroidal*/analysis ; Anti-Inflammatory Agents, Non-Steroidal*/chemistry ; Anti-Inflammatory Agents, Non-Steroidal*/isolation & purification ; Ibuprofen*/chemistry ; Ibuprofen*/analysis ; Ibuprofen*/isolation & purification ; Solid Phase Microextraction* ; Zinc*/chemistry ; Hydroxides*/chemistry; Aluminum/chemistry ; Electroplating ; Surface Properties ; Chromatography, High Pressure Liquid ; Humans ; Particle Size

In this study, in situ electrodeposition of Zn─Al-layered double hydroxides (Zn─Al-LDHs) on the surface of pencil graphite substrate were practiced with interlayer modification by ibuprofen. The prepared composite increases the efficiency of the proposed method by increasing the level of interaction between the sorbent and the selected analytes including acetylsalicylic acid and naproxen (NAP) in real sample. Eventually, the extracted target analytes were injected into high-performance liquid chromatography ultraviolet (HPLC-UV) for their measurement. The experimental design including PBD and BBD was implemented to obtain the maximize efficiency and optimal condition for extraction of the target analytes. Therefore, in optimal conditions, limits of detection of 0.33-0.64 µg L ^-1 , linear dynamic range (LDR) of 1-100 µg L ^-1 (with r ²  > 0.9934), and limits of quantification (LOQs) of 1.1-2.1 µg L ^-1 were obtained for target analytes by SPME-HPLC-UV. The intra-day relative standard deviation (RSD%) were found to range in 3.90%-5.30% (4.90%-6.80%) at concentration of 5-50 µg L ^-1 (2-10 µg L ^-1 ). According to obtained result, the relative recovery was calculated between 90% and 109%. Therefore, the obtained results showed that the selected method has a suitable performance for the preconcentration and extraction of acetylsalicylic acid and NAP in biological samples.
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University of Mazandaran, Iran

Keywords: electrodeposition; modified Zn─Al‐layered double hydroxides; nonsteroidal anti‐inflammatory drugs; solid phase microextraction

0 (Anti-Inflammatory Agents, Non-Steroidal)
WK2XYI10QM (Ibuprofen)
J41CSQ7QDS (Zinc)
0 (Hydroxides)
CPD4NFA903 (Aluminum)

Date Created: 20241106 Date Completed: 20241106 Latest Revision: 20241106

20241106

10.1002/jssc.70011

39503431