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Wando Mount Pleasant Library
11 a.m. - 6 p.m.
Phone: (843) 805-6888
Village Library
11 a.m. - 6 p.m.
Phone: (843) 884-9741
St. Paul's/Hollywood Library
11 a.m. - 6 p.m.
Phone: (843) 889-3300
Otranto Road Library
11 a.m. - 6 p.m.
Phone: (843) 572-4094
Mt. Pleasant Library
11 a.m. – 6 p.m.
Phone: (843) 849-6161
McClellanville Library
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John's Island Library
11 a.m. - 6 p.m.
Phone: (843) 559-1945
Hurd/St. Andrews Library
11 a.m. - 6 p.m.
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Folly Beach Library
11 a.m. - 1 p.m.
Phone: (843) 588-2001
Miss Jane's Building (Edisto Library Temporary Location)
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Dorchester Road Library
11 a.m. - 6 p.m.
Phone: (843) 552-6466
John L. Dart Library
11 a.m. - 6 p.m.
Phone: (843) 722-7550
Baxter-Patrick James Island
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11 a.m. - 6 p.m.
Phone: (843) 805-6930
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Combining Nitridoborates, Nitrides and Hydrides—Synthesis and Characterization of the Multianionic Sr6 N[BN2 ]2 H3 .
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- Author(s): Wandelt, Sophia L.1 (AUTHOR); Mutschke, Alexander2,3 (AUTHOR); Khalyavin, Dmitry4 (AUTHOR); Calaminus, Robert1,5 (AUTHOR); Steinadler, Jennifer1 (AUTHOR); Lotsch, Bettina V.1,5 (AUTHOR); Schnick, Wolfgang1 (AUTHOR)
- Source:
Angewandte Chemie. 12/11/2023, Vol. 135 Issue 50, p1-6. 6p.- Subject Terms:
- Source:
- Additional Information
- Abstract: Multianionic metal hydrides, which exhibit a wide variety of physical properties and complex structures, have recently attracted growing interest. Here we present Sr6N[BN2]2H3, prepared in a solid‐state ampoule reaction at 800 °C, as the first combination of nitridoborate, nitride and hydride anions within a single compound. The crystal structure was solved from single‐crystal X‐ray and neutron powder diffraction data in space group P21/c (no. 14), revealing a three‐dimensional network of undulated layers of nitridoborate units, strontium atoms and hydride together with nitride anions. Magic angle spinning (MAS) NMR and vibrational spectroscopy in combination with quantum chemical calculations further confirm the structure model. Electrochemical measurements suggest the existence of hydride ion conductivity, allowing the hydrides to migrate along the layers. [ABSTRACT FROM AUTHOR]
- Abstract: Copyright of Angewandte Chemie is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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